Ali Coskun Publications

2018

Lee, J.; Buyukcakir, O.; Kwon, T. –w.; Coskun, A.* “Energy Band-Gap Engineering of Conjugated Microporous Polymers via Acidity-Dependent in Situ Cyclization,” J. Am. Chem. Soc., 140, 35, 10937-10940.

Elabd, A.; Coskun, A.* "Dyeing Your Hair with Graphene,"Chem, 2018, 4, 661–663. [Preview article]

Byun, Y.; Coskun, A.* "Epoxy-functionalized Porous Organic Polymers via Diels-Alder Cycloaddition Reaction for Atmospheric Water Capture," Angew. Chem. Int. Ed., 2018, 57, 3173–3177. [Selected as a HOT paper] [Highlighted in ChemistryViews]

Kwon T.-w; Choi, J. W.*; Coskun, A.* "The Emerging Era of Supramolecular Polymeric Binders in Silicon Anodes," Chem. Soc. Rev., 2018, 47, 2145–2164.

 

2017

Je, S. H.; Kim, H. J.; Kim, J.; Choi, J. W.*; Coskun, A.* "Perfluoroaryl-Elemental Sulfur SNAr Chemistry in Covalent Triazine Frameworks with High Sulfur Contents for Lithium-Sulfur Batteries," Adv. Func. Mater., 2017, 27, 1703947.

 

Lee, Y. J.; Talapaneni, S. N.; Coskun, A.* "Chemically Activated Covalent Triazine Frameworks with Enhanced Textural Properties for High Capacity Gas Storage," ACS Appl. Mater. Interfaces, 2017, 9, 30679–30685.

 

Choi, S.†; Kwon, T.-w.†; Coskun, A.*; Choi, J. W.* "Highly Elastic Binders Integrating Polyrotaxanes for Silicon Microparticle Anodes in Lithium Ion Batteries," Science, 2017, 357, 279-283.

 

Lee, K.; Kim, S.; Park, J.; Park, S. H.; Coskun, A.; Jung, D. S.; Cho, W.*; Choi, J. W.* "Selection of Binder and Solvent for Solution-Processed All-Solid-State Battery," J. Electrochem. Soc., 2017, 164, A2075-A2081.

 

Talapaneni, S. N.; Kim, J.; Je, S. H.; Buyukcakir, O.; Oh, J.*; Coskun, A.* "Bottom-up Synthesis of Fully sp 2 Hybridized Three-dimensional Microporous Graphitic Frameworks as Metal-free Catalysts," J. Mater. Chem. A, 2017, 5, 12080–12085.

 

Kim, K.; Kim, S.; Talapaneni, S. N.; Buyukcakir, O.; Almutawa, A. M. I.; Polychronopoulou, K.; Coskun, A.*"Transition Metal Complex Directed Synthesis of Porous Cationic Polymers for Efficient CO2 Capture and Conversion," Polymer, 2017, 126, 296-302. [1] [Invited paper, special issue on Porous Polymers]

 

Kim, D.; Coskun, A.* "Template-directed approach towards the realization of ordered heterogeneity in bimetallic metal-organic frameworks," Angew. Chem. Int. Ed., 2017, 56, 5071–5076.

Kim, D.; Kim, D. W.; Buyukcakir, O.; Kim, M.-K.; Polychronopoulou, K.; Coskun, A.* "Highly hydrophobic ZIF-8/carbon nitride foam with hierarchical porosity for oil capture and chemical fixation of CO2," Adv. Funct. Mater., 2017, 1700706.

Buyukcakir, O.; Je, S. H.; Talapaneni, S. N.; Kim, D.; Coskun, A.* “Charged Covalent Triazine Frameworks for CO2 Capture and Conversion,” ACS Appl. Mater. Interfaces, 2017, 9, 7209–7216.

 

Kim, M.-K.; Kim, D.; Seo, J. Y.; Buyukcakir, O.; Coskun, A.* “Nanostructured ZnO as a structural template for the growth of ZIF-8 with tunable hierarchical porosity for CO2 conversion,” CrystEngComm, 2017,19, 4147–4151. [Invited paper, Themed issue on Metal-Organic Framework Catalysis]

 

Byun, Y.; Cho, M.; Kim, D.; Jung, Y.*; Coskun, A.* “Edge-functionalized Graphene Nanoribbon Frameworks for the Capture and Separation of Greenhouse Gases,” Macromolecules, 2017, 50, 523–533.

 

Talapaneni, S. N.; Lee, J. H.; Je, S. H.; Buyukcakir, O.; Kwon,T.;Polychronopoulou, K.; Choi, J. W.*; Coskun, A.* “Chemical Blowing Approach for Ultramicroporous Carbon Nitride Frameworks and Their Applications in Gas and Energy Storage,” Adv. Funct. Mater., 2017, 27, 1604658.

 

2016

Song, K. S.; Kim, D.; Polychronopoulou, K.; Coskun, A.* “Synthesis of Highly Porous Coordination Polymers with Open Metal Sites for Enhanced Gas Uptake and Separation,” ACS Appl. Mater. Interfaces, 2016, 8, 26860?26867.

 

Je, S. H.; Buyukcakir, O.; Kim, D.; Coskun, A.* “Direct Utilization of Elemental Sulfur in the Synthesis of Microporous Polymers for Natural Gas Sweetening,” Chem, 2016, 1, 482-493.

 

Je, S. H.; Hwang, T. H.; Talapaneni, S. N.; Buyukcakir, O.; Kim, H. J.; Yu, J.-S.; Woo, S. G.; Jang, M. C.; Son, B. K.; Coskun, A.*; Choi, J. W.* “A Rational Sulfur Cathode Design for Lithium-Sulfur Batteries: Sulfur-embedded Benzoxazine Polymers,” ACS Energy Lett., 2016, 1, 566–572.

 

Kim, K.; Buyukcakir, O.; Coskun, A.* “Diazapyrenium-based porous cationic polymers for colorimetric amine sensing and capture from CO2 scrubbing conditions,” RSC Adv., 2016, 6, 77406–77409.

 

Talapaneni, S. N.; Kim, D.; Barin, G.; Buyukcakir, O.; Je, S. H.; Coskun, A.* “Pillar[5]arene based conjugated microporous polymers for propane/methane separation through host-guest complexation,” Chem. Mater., 2016, 28, 4460–4466.

 

Kim, D.; Kim, D. W.; Hong, W. G.; Coskun, A* “Graphene/ZIF-8 composites with tunable hierarchicalporosity and electrical conductivity,” J. Mater. Chem. A, 2016, 4, 7710-7717.

 

2015

Kwon, T.-W†; Jeong, Y. K.†; Deniz, E.; Erhan Deniz; Al Qaradawi, S. Y.; Choi, J. W.*; Coskun, A.* “Dynamic Crosslinking of Polymeric Binders Based on Host-Guest Interactions for Silicon Anodes in Lithium Ion Batteries,” ACS Nano, 2015, 9, 11317–11324. (†Equal Contribution)

 

Talapaneni, S. N.; Buyukcakir, O.; Je, S. H.; Srinivasan, S.; Seo, Y.; Polychronopoulou, K.; Coskun, A.* “Nanoporous Polymers Incorporating Sterically Confined N-Heterocyclic Carbenes For Simultaneous CO2 Capture and Conversion at Ambient Pressure," Chem. Mater., 2015, 27, 6818–6826. [Highlighted in SYNFACTS (Synfacts, 2015, 11, 1274) as "One Stone Two Birds with a NHC Sponge"]

 

Buyukcakir, O†; Je, S. H.† ; Park, J.; Patel, H. A.; Jung, Y.; Yavuz, C. T.*; Coskun, A* “Systematic Investigation of the Effect of Polymerization Routes on the Gas Sorption Properties of Nanoporous Azobenzene Polymers,” Chem. Eur. J., 2015, 21, 15320-15327. († Equal Contribution)

 

Mara, M. W.†; Bowman, D. N.†; Buyukcakir, O.†; Shelby, M. L.; Haldrup, K.; Huang, J.; Harpham, M. R.; Stickrath, A. B.; Zhang, X.; Stoddart, J. F.; Coskun, A.*; Jakubikova, E.*; Chen, L. X.* “Electron Injection from Copper Diimine Sensitizers into TiO2: Structural Effects and Their Implications for Solar Energy Conversion Devices,” J. Am. Chem. Soc., 2015, 137, 9670–9684. († Equal Contribution)

 

Buyukcakir, O.; Seo, Y.; Coskun, A.* “Thinking Outside the Cage: Controlling the Extrinsic Porosity and Gas Uptake Properties of Shape Persistent Molecular Cages in Nanoporous Polymers,” Chem. Mater., 2015, 27, 4149–4155.

 

Song, K. S.; Coskun A.* “Catalyst-free Synthesis of Porous Graphene Networks as Efficient Sorbents for CO2 and H2,” ChemPlusChem, 2015, 80, 1127–1132. [Invited paper, Early Career Series]

 

Byun, Y.; Coskun, A.* “Bottom-up Approach for the Synthesis of a Three-Dimensional Nanoporous Graphene Nanoribbon Framework and Its Gas Sorption Properties,” Chem. Mater., 2015, 27, 2576–2583.

 

Jeong, Y. K.†; Kwon, T.-W†; Lee, I.; Kim, T.-S; Coskun, A*, Choi, J. W.* “Millipede-inspired Structural Design Principles for High Performance Polysaccharide Binders in Silicon Anodes,” Energ. Environ. Sci, 2015, 8, 1224-1230. († Equal Contribution)

Kwon, T.-W†; Jeong, Y. K. †; Lee, I.; Kim, T.-S; Choi, J. W.*; Coskun, A* “Systematic Molecular-Level Design of Binders Incorporating Meldrum`s Acid for Silicon Anodes in Lithium Rechargeable Batteries,” Adv. Mater., 2014, 26, 7979–7985. († Equal contribution)

 

2014

Kwon, T.-W†; Jeong, Y. K. †; Lee, I.; Kim, T.-S; Choi, J. W.*; Coskun, A* “Systematic Molecular-Level Design of Binders Incorporating Meldrum`s Acid for Silicon Anodes in Lithium Rechargeable Batteries,” Adv. Mater., 2014, 26, 7979–7985. († Equal contribution)

 

Byun, J.; Je, S.-H; Patel, H. A.; Coskun, A.*, Yavuz, C. T.* “Nanoporous Covalent Organic Polymers Incorporating Tröger’s Base Functionalities for Enhanced CO2 Capture,” J. Mater. Chem. A, 2014, 2, 12507–12512.

 

Kim, D. J.; Jung, Y. H.; Bharathi, K. K.; Je, S. H.; Kim, D. K.*; Coskun, A.*, Choi, J. W.* “An Aqueous Sodium Ion Hybrid Battery Incorporating Organic Compound and Prussian Blue Derivative,” Adv. Energ. Mater., 2014, 4, 1400133.

 

Jeong, Y. K.†; Kwon, T.-W.†; Lee, I.; Kim, T.-S.; Coskun, A.*; Choi, J. W.* “Hyperbranched ?-Cyclodextrin Polymer as an Effective Multidimensional Binder for Silicon Anodes in Lithium Rechargeable Batteries,” Nano Lett., 2014, 14, 864–870. (†Equal Contribution)

 

Srinivasan, S.; Je, S. H.; Back, S.; Barin, G.; Buyukcakir, O.; Guliyev, R., Jung, Y.; Coskun, A.* “Ordered Supramolecular Gels Based on Graphene Oxide and Tetracationic Cyclophanes,” Adv. Mater., 2014, 26, 2725–2729.

 

Fahrenbach, A. C.; Bruns, C. J.; Li, H.; Trabolsi, A.; Coskun, A., Stoddart, J. F.* “Ground-State Kinetics of Bistable Redox-Active Donor–Acceptor Mechanically Interlocked Molecules,” Acc. Chem. Res., 2014, 47, 482–493.

 

Patel, H. A.; Je, S. H.; Park, J.; Jung, Y.; Coskun, A.*; Yavuz, C. T.* “Directing the Structural Features of N2-Phobic Nanoporous Covalent Organic Polymers for CO2 Capture and Separation,” Chem. Eur. J., 2014, 20, 772–780.

 

2013

Cao, D.; Jurí?ek, M.; Brown, Z. J.; Sue, A. C.-H.; Liu, Z.; Lei, J.; Blackburn, A. K.; Grunder, S.; Sarjeant, A. A.; Coskun, A.; Wang, C.; Farha, O. K.; Hupp, J. T.; Stoddart, J. F. “Three-Dimensional Architectures Incorporating Stereoregular Donor–Acceptor Stacks,” Chem. Eur. J., 2013, 19, 8457–8465.

 

Barin, G.; Frasconi, M.; Dyar, S. M.; Iehl, J.; Buyukcakir, O.; Sarjeant, A. A.; Carmieli, R.; Coskun, A.; Wasielewski, M. R., Stoddart, J. F. “Redox-Controlled Selective Docking in a [2]Catenane Host,” J. Am.Chem. Soc., 2013, 135, 2466–2469.

 

Patel, H. A.; Je, S. H.; Park, J.; Chen, D. P.; Jung, Y.; Yavuz, C. T.*; Coskun, A.* “Unprecedented High-temperature CO2 Selectivity in N2-phobic Nanoporous Covalent Organic Polymers,” Nature Commun., 2013, 4, 1357.

[Highlighted in the Chemistry World on January 17, 2013, C&EN News on January 21, 2013 and KAIST Breakthroughs Newsletter (Fall 2014)]

 

Schmucker, A. L.; Barin, G.; Brown, K. A.; Rycenga, M.; Coskun, A.; Buyukcakir, O.; Osberg, K. D.;Stoddart, J. F.; Mirkin C. A. “Electronic and Optical Vibrational Spectroscopy of Molecular Tunnel Junctions Created by On-Wire Lithography,” Small, 2013, 9, 1900–1903.

 

Srinivasan, S.; Shin, W. H.; Choi, J. W.; Coskun, A.* “A Bifunctional Approach to the Preparation of Graphene and Ionic Liquid-Based Hybrid Gels,” J. Mater. Chem. A, 2013,1,43?48.

 

2012

Kim, D. J.; Je, S.-H.; Sampath, S.; Choi, J. W.*; Coskun, A.* “Effect of N-substitution in

Naphthalenediimides on the Electrochemical Performance of Organic Rechargeable Batteries,” RSC Adv., 2012, 2, 7968?7970.

 

Huang, J.; Buyukcakir, O; Mara, M. W.; Coskun, A.; Dimitrijevic, N. M.; Barin, G.; Kokhan, O.; Stickrath, A. B.; Ruppert, R.; Tiede, D. M.; Stoddart, J. F.; Sauvage, J.-P.; Chen, L. X. “Highly Efficient Ultrafast Electron Injection from the Singlet MLCT Excited State of Copper(I) Diimine Complexes to TiO2 Nanoparticles,” Angew. Chem. Int. Ed., 2012, 51, 12711–12715.

 

Coskun, A.; Spruell, J. M.; Barin, G.; Dichtel, W. R.; Flood, A. H.; Botros, Y. Y.; Stoddart, J. F. “High Hopes: Can Molecular Electronics Realise its Potential?,” Chem. Soc. Rev., 2012, 41, 4827?4859. [Highlighted as a front cover]

 

Barin, G.; Coskun, A.; Foudah, M. M. G.; Stoddart, J. F. “Mechanically Interlocked Molecules Assembled by p?p Recognition,” ChemPlusChem, 2012, 77, 159?185. [Highlighted as a front cover]

 

Coskun, A.; Hmadeh, M.; Barin, G.; Gandara, F.; Li, Q.; Choi, E.; Strutt, N. L.; Cordes, D. B.; Slawin, A.M. Z.; Stoddart, J. F.; Sauvage, J.-P.; Yaghi, O. M. “Metal-Organic Frameworks Incorporating Copper-Complexed Rotaxanes,” Angew. Chem. Int. Ed., 2012, 51, 2160?2163.

 

Avellini, T.†; Hao, L.†; Coskun, A.†; Barin, G.; Trabolsi, A.; Basuray, A. N.; Dey, S. K.; Credi, A.; Silvi, S.; Stoddart, J. F.; Venturi, M. “Photoinduced Memory Effect in a Redox Controllable Bistable Molecular Switch,” Angew. Chem. Int. Ed, 2012, 51, 1611?1615. (†Equal Contribution)

 

Fahrenbach, A. C.; Barnes, J. C.; Lanfranchi, D. A.; Li, H.; Coskun, A.; Gassensmith, J. J.; Liu, Z.; Benitez, D.; Trabolsi, A.; Goddard, W. A.; Elhabiri, M.; Stoddart, J. F. “Solution-Phase Mechanistic Study and Solid-State Structure of a Tris (Bipyridinium Radical Cation) Inclusion Complex,” J. Am. Chem. Soc. 2012, 134, 3061?3072.

 

Coskun, A.; Banaszak, M.; Astumian, R. D.; Stoddart, J. F.; Grzybowski, B. A. “Great expectations: Can Artificial Molecular Machines Deliver on Their Promise?,” Chem. Soc. Rev., 2012, 41, 19?30. [Highlighted as a front cover and also in Sciencenewsline on November 25, 2011, R&D Magazine on November 28, 2011, AZO NANO on November 29, 2011 and C&EN News on April, 2 2012]

 

2011

Li, H.; Fahrenbach, A. C.; Coskun, A.; Zhu, Z.; Barin, G.; Zhao, Y.-L.; Botros, Y. Y.; Sauvage, J.-P.; Stoddart, J. F. “A Light-Stimulated Molecular Machine Driven by Radical Pairing Interactions in Water,”Angew. Chem. Int. Ed., 2011, 50, 6782–6788. [Highlighted as an inside cover]

 

Dey, S. K.; Coskun, A.; Fahrenbach, A. C.; Barin, G.; Basuray, A. N.; Trabolsi, A.; Stoddart, J. F. “A Redox-Active Reverse Donor-Acceptor [2]Rotaxane,” Chem. Sci., 2011, 2, 1046–1053.

 

Coskun, A.; Spruell, J. M.; Barin, G.; Fahrenbach, A. C.; Forgan, R. S.; Colvin, M. T.; Carmielli, R.; Benítez, D.; Tkatchouk, E.; Friedman, D. C.; Sarjeant, A. A.; Wasielewski, M. R.; Goddard III, W. A.; Stoddart, J. F. “Mechanically Stabilized TTF Radical Dimers,” J. Am. Chem. Soc., 2011, 133, 4538–4547.

 

Basu, S.; Coskun, A.; Friedman, D. C.; Olson, M. A.; Benítez, D.; Tkatchouk, E.; Barin, G.; Yang, J.; Fahrenbach, A. C.; Goddard, W. A.; Stoddart, J. F. “Donor Acceptor Oligorotaxanes Made to Order,” Chem. Eur. J., 2011, 17, 2107–2119. [33] [Highlighted in Angewantde Chemie (Angew. Chem. Int. Ed., 2011, 50,1466?1468)]

 

Barin, G; Coskun, A.; Friedman, D. C.; Olson, M. A.; Colvin, M. T.; Carmielli, R.; Dey, S. K.; Bozdemir, O. A.; Wasielewski, M. R.; Stoddart, J. F. “A Multistate Switchable [3] Rotacatenane,” Chem. Eur. J., 2011,17, 213?222. [Highlighted in the front cover of 2011 Year of Chemistry Issue]

 

2010

Han, S.; Wei, Y.; Valente, C.; Lagzi, I.; Gassenmith, J. J.; Coskun, A.; Stoddart, J. F.; Grzybowski, B. A.“Chromatography in a Single Metal-Organic Framework (MOF) Crystal,” J. Am. Chem. Soc., 2010, 132,16358–16361. [Highlighted in the Chemistry World on November 4, 2010]

 

Han, S.; Wei, Y.; Valente, C.; Forgan, R. S.; Gassenmith, J. J.; Smaldone, R. A.; Nakanishi, H.; Coskun, A.; Stoddart, J. F.; Grzybowski, B. A. “Imprinting Chemical and Responsive Micropatterns into Metal-Organic Frameworks,” Angew. Chem. Int. Ed., 2010, 50, 276?279.

 

Stephenson, R. M.;Wang, X.; Coskun, A.; Stoddart, J. F.; Zink, J. I. “Excited State Distortions Caused by Photochemical Electron Transfer in a Donor-Acceptor [2]Rotaxane,” Phys. Chem. Chem. Phys., 2010, 12, 14135?14143.

 

Spruell, J. M.†; Coskun, A.†; Friedman, D. C.; Forgan, R. S.; Sarjeant, A. A.; Trabolsi, A.; Fahrenbach, A.C.; Barin, G.; Paxton, W. F.; Dey, S. K.; Olson, M. A.; Benítez, D.; Tkatchouk, E.; Colvin, M. T.; Carmielli, R.; Caldwell, S. T.; Rosair, G. M.; Hewage, S. G.; Duclairoir, F.; Seymour, J. L.; Slawin, A. M. Z.; Goddard III, W. A.; Wasielewski, M. R.; Cooke, G; Stoddart, J. F. “Highly Stable TTF Radical Dimers in[3]Catenanes,” Nature Chem., 2010, 2, 870-879. (†Equal Contribution)

 

Olson, M. A.; Coskun, A.; Fang, L.; Basuray, A. N.; Stoddart, J. F. “Polycatenation Under Thermodynamic Control,” Angew. Chem. Int. Ed., 2010, 49, 3151-3156.

 

Coskun, A.; Wesson, P. J.; Klajn, R.; Trabolsi, A.; Fang, L.; Olson, M. A.; Dey, S. K.; Grzybowski, B. A.; Stoddart, J. F. “Molecular-Mechanical Switching at the Metal Nanoparticle-Solvent Interface,” J. Am. Chem. Soc., 2010, 132, 4310?4320.